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Over the past year our research group reported the synthesis of two different classes of N,C-organoboron chelate compounds,each possessing a unique photoresponse upon the irradiation of UV light.In the case of the five membered ring chelate system,photoisomerization was observed wherein a sequential multi-step transformation ultimately led to the controllable inversion of stereochemistry at the chiral centre on the azole heterocycles.In the case of the six membered ring chelate systems,photoelimination of a mesitylene molecule led to the formation of the corresponding 1,2-azaborines.This talk will highlight our recent efforts in exploring the generality of these photo-transformations.Both the synthesis and examination of photo-responses for analogous organoboron chelates will be disclosed.