Two unique cobalt-organic frameworks based on substituted imidazole-dicarboxylate and dipyridyl-type

来源 :2016年中西部地区无机化学化工学术研讨会 | 被引量 : 0次 | 上传用户:XPTRY
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  Two three dimensional (3D) Co(Ⅱ) coordination polymers incorporating similar substituted imidazole-dicarboxylate and dipyridyl-type ancillary ligands pillared layer,namely,{Co3(mimda)2(bpe)3·3H2O}n (1) and {Co3 (eimda)2(bipy)3·8H2O}n (2) have been successfully afforded (H3mimda = 1H-2-methyl-4,5-imidazoledicarboxylic acid,while H3eimda = 1H-2-ethyl-4,5-imidazole-dicarboxylic acid,bpe = 1,2-di(4-pyridyl) ethylene and bipy = 4,4'-bipyridine).
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