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阴离子与过渡金属阳离子表现出相似的配位化学规律,如特定的配位几何与配位饱合性.近年来,我们发展的一系列多脲配体对四面体含氧酸根,特别是磷酸根离子,展现出良好的配位性能,这类配体通过组合螯合效应和空间匹配效应能够有效而完美的相互作用.
阴离子配位的超分子组装及其应用
【摘 要】
：
阴离子与过渡金属阳离子表现出相似的配位化学规律,如特定的配位几何与配位饱合性.近年来,我们发展的一系列多脲配体对四面体含氧酸根,特别是磷酸根离子,展现出良好的配位性能,这类配体通过组合螯合效应和空间匹配效应能够有效而完美的相互作用.
【机 构】
：
西北大学化学与材料科学学院,陕西西安学府大道1号,710127
【出 处】
：
第七届全国物理无机化学会议
【发表日期】
：
2016年7期
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