【摘 要】
：
A metal-free oxidative trifluoromethyl-thiolation of terminal alkynes using readily available CF3SiMe3 and elemental sulfur at room temperature has been developed.This reaction provides an efficient a
【机 构】
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Key Laboratory of Organofluorine Chemistry,Shanghai Institute of Organic Chemistry,Chinese Academy o
【出 处】
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The 24th International Society of Heterocyclic Chemistry Con
论文部分内容阅读
A metal-free oxidative trifluoromethyl-thiolation of terminal alkynes using readily available CF3SiMe3 and elemental sulfur at room temperature has been developed.This reaction provides an efficient and convenient method for the preparation of alkynyl trifluoromethyl sulfides bearing a wide range of functional groups.Preliminary investigation revealed that elemental sulfur instead of air acted as the oxidant.
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