Symmetry Strategy to Enhance the Magnetic Anisotropy of Single-Molecule Magnets

来源 :第十届国际华人无机化学研讨会 | 被引量 : 0次 | 上传用户：wyzhen

【摘要】

：

Inspired by the large intrinsic magnetic anisotropy of heavier lanthanide ions, great synthetic efforts have been devoted to, not only the pure 4f or 5f, but al

【作者】

：

Jun-Liang Liu Jie-Yi Wu Yan-Cong Chen Ming-Liang Tong

【机构】

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SchoolofChemistryandChemicalEngineering,SunYat-SenUniversity,Guangzhou,510275

【出处】

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第十届国际华人无机化学研讨会

【发表日期】

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2014年12期

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Inspired by the large intrinsic magnetic anisotropy of heavier lanthanide ions, great synthetic efforts have been devoted to, not only the pure 4f or 5f, but also 3d-4f/5f clusters since 2003.1 However, the largest energy barrier for a 3d-4f SMM is only 38.6 K before 2012 and was recently improved to 118 K2a and 142 K2b.

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Symmetry Strategy to Enhance the Magnetic Anisotropy of Single-Molecule Magnets

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