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As a discourse attempt of the complex science management, Social coordination following systematic thinking as well as the "18151" theoretical system of the complex scientific management,innovatively establishes social coordination model and puts forward a series of new concepts of social entities.It divides social entities into "group, subject, receptor, auxiliary and object" (generally named "synergy five entities"), corresponding to "driving-force, motility-force, impetus-force, pulling-force and compensatory-force" (generally named "synergy five forces").With quantitative analysis, strong operational methods and portable advantages, the social coordination model makes up the deficiencies of Porters five forces analysis model.As the application analysis of social coordination, college students entrepreneurial management with the macro and micro analysis methods as well as qualitative and quantitative analysis methods adopts the social coordination model, integrates the entrepreneurship resource.It tries to achieve entrepreneurial target and solve the problem of college students entrepreneurship.