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Organic electronics are promising and future candidates for the applications of cathode in green LIBs.Herein,polyimide-graphene nanocomposite(PI-FLEG)is developed by simple in situ polymerization in a well dispersed graphene sheets.Electronic properties of the PI-FLEG are significantly increased with graphene additives and utilized efficiently the electrochemical performance of the pure polyimide.When employed as cathode in LIBs,can deliver a discharge capacity of 177 mAh g-1 at 0.1 C and retains 149 mAh g-1.