三价锰引发的膦自由基与碳碳不饱和键的选择性反应研究

来源 :第十届全国物理有机化学学术会议 | 被引量 : 0次 | 上传用户：bluelee530

【摘要】

：

有机膦化合物广泛存在于自然界,具有一定的生理活性,在医药和农药方面有着广泛的用途.[1]有机膦化合物具有很强的配位能力,它在配位化学和材料化学方面也有着广阔的应用前景.

【作者】

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李大鹏潘向强周少方邹建平

【机构】

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苏州大学材料与化学化工学部有机化学省重点实验室江苏省苏州市仁爱路199号215123

【出处】

：

第十届全国物理有机化学学术会议

【发表日期】

：

2013年9期

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有机膦化合物广泛存在于自然界,具有一定的生理活性,在医药和农药方面有着广泛的用途.[1]有机膦化合物具有很强的配位能力,它在配位化学和材料化学方面也有着广阔的应用前景.[2]因此,开发有机膦化合物的新合成方法很有意义.本论文介绍了以下几方面的工作:1)醋酸锰促进的二苯基氧膦和芳基炔烃的选择性反应;2)膦自由基和4-联苯基丁烯酸乙酯的选择性反应;3)K-OMS-2催化的亚膦酸酯与二芳基炔酯的选择性加成成环反应;4)醋酸锰引发的膦自由基分子内反应合成二苯并磷杂环戊二烯衍生物,结果表明以上反应都具有很好的选择性和产率.

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三价锰引发的膦自由基与碳碳不饱和键的选择性反应研究

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