The first carbonyl bond dissociation energies of Fe(CO)5-y(PR3)y( y=0-4) : The role of the phosphine

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  Iron carbonyl complexes have been found with wide applications in organometallics chemistry due to their effective catalytic performance,low price and environmentally friendly.However,the low selectivity of Fe(CO)5 limits its implication.Phosphine ligands exhibit high coordination ability and stereoselectivity.We want to examine the influence of phosphine ligands on the properties of Fe(CO)5-y(PR3)y.
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