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Crystalline metal-organic frameworks (MOFs) are formed by reticular synthesis, which creates strong bonds between inorganic units and organic linkers.The constituents of MOFs have been widely varied to yield crystals of ultrahigh porosity, high thermal and chemical stability.These characteristics allow the interior of MOFs to be chemically altered for use in gas separation/storage,and catalysis.MOFs whose chemical composition and shape of building units can be multiply varied within a particular structure have become a reality and the basis for providing properties where the whole performs better than the sum of the parts.This lecture will give an overview of MOF chemistry and its applications to clean energy.