【摘 要】
：
Fibril crystal growth of diblock copolymers is meaningful in the fields of nanotechnology [1] and neurodegenerative diseases [2].We report dynamic Monte Carlo simulations of a lattice model of diblock
【机 构】
：
School of Chemistry and Chemical Engineering,State Key Lab of Coordination Chemistry,Nanjing Univers
【出 处】
：
Seventh International Symposium On Engineering Plastics (第七届
论文部分内容阅读
Fibril crystal growth of diblock copolymers is meaningful in the fields of nanotechnology [1] and neurodegenerative diseases [2].We report dynamic Monte Carlo simulations of a lattice model of diblock copolymers performing the crystallization-driven fibril-micelle growth under two circumstances of solutions: sporadic crystals with the feeding mode of constant polymer concentrations,and massive crystals with the depleting mode of decaying polymer concentrations [3].We found that anisotropic driving forces arc a prerequisite condition of steady growth of fibril crystals.In addition,lamellar crystal width is confined by the non-crystalline block below a critical concentration that shifts down with the decrease of the non-crystallizable block fractions.
其他文献
Polymer solar cells (PSCs) have attracted considerable interests in making larger-area devices through roll-to-toll printing process for its advantage of low-cost and rich raw materials.Bulk heterojun
Carbon composites using polymer resins as binder and carbon black or mesophase pitch as additives were investigated aiming to develop optimum compositions with advanced performance in manufacture new
Dental caries and dental erosion are two major problems of oral health.In comparison to dental caries, which have been well controlled by fluoride, dental erosion, tooth mineral loss due to the acid,
Time-of-flight secondary ion mass spectrometry (ToF-SIMS) spectra of polystyrene (PS)1 and poly (2,3, 4, 5, 6-pentafluorostyrene) (5FPS)2 films supported on silicon wafers were obtained at temperature
Nature has used brush like soft matters and hydration lubrication to achieve ultra-low friction even at high Herzian pressure, such as in articular cartilage.Inspired by this, people have used polymer
In this work, we present rheological study on the linear and nonlinear viscoelasticity of polymer/silica nanocomposites.It is well known that network of particle agglomerates can form when the content
Since free ends play an important role in the motion of entangled polymers (reptation, fluctuations),examining the behaviour of ring polymers (which have no beginning or end) is a challenge.In fact,th
Supramolecular polymer networks are formed by non-covalent associative interactions between polymer chains.The reversibility of the crosslinks leads to a wide range of potential applications of these
Strongly segregated polyethylene-b-polystyrene (PE-b-PS) diblock copolymers were infiltrated within anodic aluminum oxide nanoporous templates (AAO) (with 60 nm diameter).After carefully removing the
Side-chain polymers (SCPs) may form columnar liquid crystalline (φ) phase.Considering the topological preorder in one dimension the linear chains may select naturally the φ phase when they intend to s