膨胀型钢结构防火涂层耐湿热性能的理论分析与机理研究

来源 :第3届耐高温防火涂料研讨会 | 被引量 : 0次 | 上传用户:everywherecsu
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为考察膨胀型钢结构防火涂层的湿热老化机理及在湿热环境下防火涂层防火隔热性能随使用时间的变化规律,对隔热性能试验的试验结果进行了计算和总结.并通过傅里叶红外光谱检测和炭化层结构的扫描电镜对U型、A型这2种膨胀型钢结构防火涂料进行了湿热老化机理分析.结果表明;涂层发生老化是由于涂层内的亲水性物质向涂层表面迁移和析出:U型、A型这2种涂层的等效导热系数随老化时间延长总体上均呈现出增大的趋势,且增幅与涂料的基体树脂和阻燃体系的组分有关;经过42次湿热老化循环后,U型涂层等效导热系数增加了50%以上,A型涂层等效导热系数的增幅超过了100%,而厚度不同的A型涂层其等效导热系数的变化规律有所区别.
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