Lewis酸催化的N-Ts-2-芳基吖丙啶与吲哚的不对称[3+2]环化反应

来源 :中国化学会第九届全国有机化学学术会议 | 被引量 : 0次 | 上传用户：Iknowyou

【摘要】

：

氮杂三元环(吖丙啶)的不对称开环反应是制备含氮手性化合物的重要方法,也是具有非常大的挑战性的课题之一.本领域中,前人研究所取得的成功的例子主要局限在对于内消旋吖丙啶(meso-aziridines)去对称化反应的研究上,[1] 而对于2-取代的吖丙啶的不对称反应的成功例子很少,且使用简单手性Lewis 酸催化的体系更未见报道.

【作者】

：

柴卓朱佑民杨培俊王少印王绍武刘珍杨高升

【机构】

：

功能分子固体教育部重点实验室,安徽省分子基材料实验室,安徽师范大学化学与材料科学学院,安徽省芜湖市北京东路1号,241000

【出处】

：

中国化学会第九届全国有机化学学术会议

【发表日期】

：

2015年7期

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Lewis酸催化的N-Ts-2-芳基吖丙啶与吲哚的不对称[3+2]环化反应

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