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Infiltration has been widely employed to fabricate composite electrodes in SOFC.However,few systematic investigations exist on oxygen reduction and reaction(ORR)mechanisms in infiltrated SOFC cathodes.In this presentation,we report our studies on several key issues related to infiltrated cathode:Characterizing Surface Exchange Behavior: The oxygen surface exchange coefficient(k)and diffusivity(D)values for various mixed-ionic electronic conductors(MIECs)have been widely reported in the literatures,by either electrical conductivity relaxation(ECR)or isotope exchange(IE)methods.