Co/Ni修饰钒多酸的合成及其结构

来源 :第九届全国无机化学学术会议 | 被引量 : 0次 | 上传用户：balonbalon

【摘要】

：

由于含有过渡金属的多金属氧簇在C-H键活化构建C-N键的催化反应中具有重要应用,因此引起了化学家的广泛关注[1],过渡金属修饰的多金属氧簇研究也日益成为多酸化学性能研究的一个热点[2].对于过渡金属Co/Ni-POV的二元体系多金属氧簇尚未见文献报道,我们通过简单的一锅法合成了两个过渡金属修饰的钒多酸：[Co(H2O)5]2V10O28,[Ni(H2O)5]2V10O28.

【作者】

：

黄现强窦明煜杨欣欣燕彩鑫李大成窦建民

【机构】

：

聊城大学化学化工学院,山东聊城,252059 山东省化学储能与新型电池技术重点实验室,山东聊城,2

【出处】

：

第九届全国无机化学学术会议

【发表日期】

：

2015年7期

【关键词】

：

钒多酸过渡金属晶体结构

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Co/Ni修饰钒多酸的合成及其结构

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