Impacts of Calcium Sulfate on the Hydration of Calcium Aluminate Cement-Portland Cement Blends at Di

来源 :The 14th International Congress on the Chemistry of Cement ( | 被引量 : 0次 | 上传用户:llizhixiong
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  The present study focus on the effect of curing temperature on the hydration of calcium aluminate cement (CAC) dominated ternary binders at 0, 10, 20 and 40℃.Two varieties of calcium sulfate are employed, including α-hemihydrate and natural anhydrite.The effects of temperature on the phase development, together with microstructure change of pastes within 3 days were systematically determined by X-ray diffraction (XRD),backscattered electron imaging (BEI) and mercury intrusion porosimeter (MIP).Results show that higher temperature accelerates the 1-day strength prominently, while it has no obvious contribution to the later age strength.Furthermore, though the main hydration products are relating to calcium (sulpho)aluminate related phases, raising temperature leads to a rapider conversion from ettringite to plate-like monosulfate, and higher amount of coarser pores for pastes with anhydrite after 3 days, but finer pores for those pastes with α-hemihydrate.Additionally, stratlingite (C2ASH8) and aluminium hydroxide also form at 40℃ in those pastes with anhydrite compared with binders containing α-hemihydrate.
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