Electrochemical study and application on rutin at chitosan/graphene films modified glassy carbon ele

来源 :第一届当归国际学术研讨会 | 被引量 : 0次 | 上传用户:gaolch007
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  Graphene (G) was dispersed into 0.5% chitosan (Chit) solution, then the composite films were coated on glassy carbon electrode (GCE), the electrochemical behavior of rutin on a Chit/G modified GCE was investigated and the electrochemical parameters of rutin were calculated.Rutin effectively accumulated on the Chit/G/GCE and caused a pair of redox peaks at around 408 mV and 482 mV (vs.SCE) in 0.1 M phosphate buffer solution (pH 4.0).Under optimized conditions, the anodic peak current was linear to the rutin concentration in the range of 5 × 10-7-1.04 × 10-5 M.The regression equation was: y=9.9219x-0.0025, r=0.9958.The proposed method was successfully used for the determination of rutin content in tablet samples with satisfactory results.
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