SrAlSi4N7荧光粉的结构、形貌及发光性能研究

来源 :第十四届全国发光学学术会议 | 被引量 : 0次 | 上传用户:zmm520111
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  为了改善目前黄色荧光粉显色指数低的问题,合成了Ce3+,Eu2+掺杂的SrAlSi4N7 黄色荧光粉.其发射光谱中包含了黄绿光(530 nm)、橙黄光(580 nm)和红光(630 nm)三个发光中心,可以将LED 的显色指数提高到88.
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本文采用高温固相法、以H3BO3 作为助熔剂在1500℃下合成了一种新型的农膜用红色转光剂Sr2MgAl22O36:Mn4+,(M)(M=Li+,Na+,K+,Cl-),研究了转光剂的晶体结构、发光特性、紫外-可见吸收,能量传递机理,不同助溶剂的作用以及正一价阳离子(Li+,Na+,K+)的电荷补偿作用。研究表明:Sr2MgAl22O36:Mn4+红色转光剂的发射峰为643 nm 和658 nm,