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The PCs with high strength were prepared from latex spheres with a hard PS core and an elastometric PMMA/PAA shell.The mono-dispersed latex spheres were synthesized via one-step emulsion polymerization without purification [1a].PC films with brilliant colours covering the wavelength period from the UV to the IR can be fabricated over large areas by vertical deposition method and even spray coating [1b,1c,1d].