1 Introduction The oxidation of alcohols to their corresponding aldehydes,ketones or carboxylic acids is of significant importance in organic chemistry,and the oxidation products represent important intermediates for the preparation of a various of other compounds[1,2].Catalytic oxidation methods,which employ a variety of metal-containing catalysts,such as Cu (Ⅰ)[3] and so on,developed quickly in recent decades.However,most of the metal containing catalysts are expensive and the reactions generally used the oxidant which may lead to the environmental pollution. 1 Introduction The oxidation of alcohols to their corresponding aldehydes, ketones or carboxylic acids is of significant importance in organic chemistry, and the oxidation products represent important intermediates for the preparation of a variety of other compounds [1,2] .Catalytic oxidation methods, which employ a variety of metal-containing catalysts, such as Cu (I) [3] and so on, developed rapidly in recent decades. However, most of the metal containing catalysts are expensive and the reaction generally used the oxidant which may lead to the environmental pollution.