The rational design of the octacyanometallate-based MoVFeⅡ organic–inorganic hybrid spin crossover materials in different dimensional are attracting great attention for both fundamental interests(swit
Self-assembly is a powerful technique for the bottom-up construction of discrete,well-defined nanoscale structures.The self-assemble of high symmetric polynuclear compounds have increased greatly due
Manipulating metal-to-metal charge transfer(MMCT)property provides a promising approach for obtaining switchable multi-functional materials.The previous researches mainly focused on the chemical modif
Spin-crossover(SCO)complexes,which can be responsive to external stimuli such as temperature,pressure and light irradiation,will be a promising candidate in ultrahigh-density information storage techn
A new chiral metal-organic framework with 3D network,[Zn((R)-CBA)2(4-bpdb)]n(1),has been synthesized and characterized by single-crystal X-ray diffraction.
The polynuclear transition metal clusters have attracted considerable attention due to their potential application in such fields,for example,materials science,bioinorganic chemistry,and catalysis.