Six-coordinate nitrato complexes of Co-porphyrins.Oxygen atom transfer from nitrate to free nitric o

来源 :2015年生物多样性与生态系统国际研讨会 | 被引量 : 0次 | 上传用户:learner1
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  Six-coordinate nitrato complexes of Co-porphyrins can be obtained at low temperatures by nitric oxide (NO) dioxygenation reaction upon NO interaction with specially constructed 6-coordinate dioxygen complexes of Co-porphyrins with trans electronodonor ligands (L)Co(Por)(O2) that represent the models of oxy-coboglobins' active center.
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