The studies on molecular materials with optical, electronic and magnetic properties have developed rapidly[1-2].Combining metal and nitronyl nitroxide radical within the same molecular entity is one o
In this work,two series of new lanthanide metal-organic frameworks(Ln-MOFs),{[Ln(L)1.5(H2O)]·DMA·4H2O}n(1-Ln,Ln = Tb,Gd,Dy)and {[La2(L)3]·4H2O}n(2-La),have been successfully assembled by Ln3+ions and
By treating a semirigid 5-oxyacetate isophthalic acid(H3OAIP)ligand with MnSO4/CoSO4/CdSO4 under solvothermal conditions,three isostructural cluster organic frameworks,[M2(OH)(OAIP)(DMA)]·H2O(M=Mn2+(1
A new three-dimensional(3D)luminescent metal-organic framework(MOF)[Zn2(L)2]·2DMA·3H2O(1)[H2L = 2-(imidazol-1-yl)terephthalic acid] have been solvothermally synthesized by d10 Zn(Ⅱ)ions and H2L in dif
A series of alkaline earth-metal organic frameworks(AE-MOFs),i.e.{[Mg2(μ6-L)(μ2-OH2)(H2O)4]·DMF}n(1),[Ca2(μ10-L)(EtO)]n(2),[Sr(μ6-H2L)(MeO)]n(3)and {[Ba1.5(μ5-H2L)(μ4-H3L)(H2O)3]·2(H2O)}n(4)were synth