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A new 3D metal-organic framework(MOF),[Gd(BPT)(DMF)(H2O)·(H2O)0.5](1)(DMF = N,N′-dimethylformamide)has been synthesized by self-assembly of gadolinium(Ⅲ)nitrate and biphenyl-3,4',5-tricarboxylate(H3BPT)under solvothermal reaction.