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In this research contribution,a novel hybrid nanofiber containing nanoSiO2-carried europium complex nanocrystals [SiO2:Eu(tta)3phen] (htta:α-thenoyltrifluoroacetone;phen:1,10-phenanthroline) in polymethyl methacrylate(PMMA) have been achieved by electrospinning technique.