ELECTROCHROMIC METALLOPOLYMER FILM PREPARED BY OXIDATIVE ELECTROPOLYMERIZATION OF THE FE(Ⅱ)-TERPYRID

来源 :10th IUPAC International Conference on Novel Materials and t | 被引量 : 0次 | 上传用户：sophia_yin104

【摘要】

：

【作者】

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DONGFANG QIU XIAOYU BAO HONGWEI WANG YUQUAN FENG KECHENGLIU

【机构】

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College of Chemistry and Pharmacy Engineering,Nanyang Normal University,Nanyang,473061,P.R.China

【出处】

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10th IUPAC International Conference on Novel Materials and t

【发表日期】

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2014年3期

【关键词】

：

electropolymerization Fe(Ⅱ)-Terpyridine complex triphenylamine metallopolymer el

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A functionalized complex [Fe(L)2](PF6)2 {L =4-[p-(diphenylamino)phenyl)]-2,2:6,2"-terpyridine} has been synthesized and confirmed successfully.Its oxidative electropolymerization has been conducted by continuous cycling of the working electrode potential from 0 to 1.8 V in 0.1 mol·L-1 Bu4NClO4/CH3CN solution containing 5.0× 10-4 molL-1 monomer.The purple hybrid polymer film exhibits a non-diffusional charge transfer behavior of Fe(Ⅲ)/Fe(Ⅱ)couple and an irreversible redox process of phenylamine moiety on the Pt working electrode,as well as high stability in monomer-free electrolytic solution.

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ELECTROCHROMIC METALLOPOLYMER FILM PREPARED BY OXIDATIVE ELECTROPOLYMERIZATION OF THE FE(Ⅱ)-TERPYRID

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