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In 5d transition metal compounds,novel properties arise from the interplay of electron correlations and spin-orbit interactions.In this talk,we briefly review our theoretical works relating to 5d compounds: the topological Weyl-Semimetal in pyrochlore iridates,the Axion insulatior in spinel osmates,the Slater insulator in perovskite osmates.We also discuss the novel properties of WTe2.