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Mesoporous carbons are useful for a range of applications such as separations,electrochemistry and catalysis.A route to prepare porous materials is through cooperative self-assembly of a carbon precursor (e.g.phenolic resin) and a block copolymer,in which the precursor is selectively soluble,to drive mesophase formation.This talk will discuss our recent efforts in block copolymer templating to produce novel mesoporous carbon films from advanced templates and processing approaches.