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Organometallic Ru(Ⅱ)/Os(Ⅱ)arene complexes of the type [(··6-arene)Ru(en)Cl]+,1 where the arene = e.g.p-cymene,biphenyl(bip)or tetrahydroanthracene(tha)and en = ethylenediamine,are toxic to cancer cells,including cisplatin-resistant cell lines.