论文部分内容阅读
本文采用水热合成法，以{P4Mo6}磷钼酸盐为基本构筑单元，通过引入主族元素Na 和有机配体乙二胺，成功合成了一例沙漏型[Na(P4Mo6O31)2]化合物。通过X-射线单晶衍射、IR、TG、XRD、XPS 等测试进行了结构表征。
沙漏型[Na(P4Mo6O31)2]磷钼酸盐的合成与催化性质
【摘 要】
：
本文采用水热合成法，以{P4Mo6}磷钼酸盐为基本构筑单元，通过引入主族元素Na 和有机配体乙二胺，成功合成了一例沙漏型[Na(P4Mo6O31)2]化合物。通过X-射线单晶衍射、IR、TG、XRD、XPS 等测试进行了结构表征。
【机 构】
：
河北师范大学,化学与材料科学学院,石家庄,050024
【出 处】
：
中国化学会第八届全国配位化学会议
【发表日期】
：
2017年10期
其他文献
The public reputation of carbon monoxide(CO)as an invisible killer,which long known as a gas that is toxic to humans.But now it has been confirmed as a very important molecule in the biological system
Metal-radical based complexes[1-3],especially 2p-3d-4fhetero-tri-spin compounds[4],have attracted much attention due to their high ground states from the uncompensated spins and the novel properties w
本文使用2-(2-吡啶基)-苯并咪唑(PBM)为配体与稀土离子构筑三个同构的稀土配合物[Ln(hfac)3(PBM)](Ln = Dy,Tb,Gd；hfac = 1,1,1,5,5,5-六氟乙酰丙酮)。
Syntheses,Structural Characterization and Photoluminescence Properties of Rare-Earth-Organotin Conta
Heterometallic polyoxometalates have become one of the most rapidly growing and challengeable field of polyoxometalate chemistry owe to their unparalleled structural diversities and potential applicat
Histidine imidazole plays an important role in the synthesize of numerous metalloproteins[1].Therefore,complexes with imidazole or benzimidazole structure are attracted a great deal of attention,espec
Crystal structure and luminescence of Zn(Ⅱ)polymer constructed from rigid arenesulfonate and flexibl
Researches on Zn(Ⅱ)coordination polymers with the mixed organic ligands have attracted intensive interests in crystal engineering and coordination chemistry,which is not only ascribed to their potenti
以乙基香兰素为母体,设计合成一种乙烯基羧酸香兰素配体(G2)。由于羧基与Sn(Ⅳ)具有很好的配位能力 [1,2]。该配体分别不一丁基氧化锡,二丁基氧化锡,三丁基氧化锡反应,得到三种羧基锡配合物(G2P1,G2P2 和 G2P3),通过红外光谱、核磁共振谱、质谱、元素分枂、单晶X-射线衍射等分枂手段对合成的配合物迚行表征。収现该系列锡配合物在近红外匙有双光子吸收,通过共聚焦显微成像系统研究了它们在抗
Polyoxometalates(POMs)as an effective green photocatalysts for the reduction of environmental pollution have attracted extensive interest during the last few decades due to their excellent photochemic
利用金属-碳键构筑超分子功能体系是有机金属化学发展较快的领域之一[1]。近年来我们通过引入有机金属构筑基元，制备了系列具有不同空间结构和形状的有机金属功能体系，发现了氢气诱导复杂有机金属化合物的高效制备与可逆转化[2]。
Synthesis and structural diversity of alkali-metal(Li,Na,K)alkyl magnesiates containing bidentate am
The advantages of bimetallic "ate" complexes have over conventional alkali metal reagents(use of milder reaction conditions,better functional group tolerance,access to hitherto inaccessible synthetic