The development of porous metal–organic frameworks(MOFs) that can retain structural integrity under harsh physical and chemical conditions is essential if they are considered as candidates for use in
The first thorium framework compound with mixed-valent phosphorus based ligands phosphite and pyrophosphate,[BMMim]2[Th3(PO3)4(H2P2O7)3](ThP-1),was synthesized from ionothermal reaction concurrent wit
Multifunctional materials combing both single molecule magnet(SMM) behavior and smarttunable luminescent properties have attracted great attentions in the fields of physics,chemistry and material scie
Supramolecular aggregates with desirable nanostructures andfunctionalities are widely used as biological materials for bio-imaging,theranostics of diseases,regenerative medicine,etc.
Metal organic frameworks(MOFs),formed by the virtually limitless selection of metals and bridging ligands,have attracted much attention due to their versatile molecular architectures and widespread ap
Molecule-based magnets have achieved considerable attention in recent years because of their many interesting and potentially available magnetic behavior.
Porphyrin(Por) and subhthalocyanine(SubPc) chromophores have been fused through the benzo[α]pyrazine moiety,resulting in the first hybridized Por-SubPc-fused dimer with a unique plane-bowl molecular s
Currently,the study of lanthanide-based single molecule magnets(SMMs)has become one of the research hotspots of the molecule magnetism.[1,2] In this paper,a series of Dy4 clusters,[Dy4(acac)4(L)6(μ3-O
One inorganic-organic hybrid compound(C3H12N2)2[Cu(H2O)4(SO4)2](HSO4)2(1) has been synthesized based on the 1,3-propanediamine as the template under the slow evaporation condition.