Probing the Influence of Phosphonate Bonding Modes to Uranium(Ⅵ)on Structural Topology and Stability

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  Systematic control of the reactions between U(Ⅵ)and 1,4-phenylenebis(methylene))bis(phosphonic acid)(pmbH4)allows for alterations in the bonding between these constituents,and affords three new uranyl phosphonate compounds with chiral-1D,2D,and 3D structures,namely [TPA][UO2(pmbH3)(pmbH2)H2O]·2H2O(1)(TPA= NPr4+),[NH4]2[UO2(pmb)](2),and UO2(pmbH2)(3).
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