【摘 要】
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In this article,five compounds {[BHMTA] [Cu2(SCN)3]}n(1),{[BHMTA] [Cu2I3]}n(2),{[BHMTA]2[CdI4]}(3)and {[BHMTA]2[Pb2I6]}n(4)were successfully synthesized via the self-assembly ofmetal salts and N-benzy
【机 构】
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College of Chemistry and Molecular Engineering,Zhengzhou University,Henan 450001,P.R.China
【出 处】
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中国化学会第十六届全国有机合成化学学术研讨会
论文部分内容阅读
In this article,five compounds {[BHMTA] [Cu2(SCN)3]}n(1),{[BHMTA] [Cu2I3]}n(2),{[BHMTA]2[CdI4]}(3)and {[BHMTA]2[Pb2I6]}n(4)were successfully synthesized via the self-assembly ofmetal salts and N-benzylhexamethylenetetramine bromide(BHMTA)at room temperature.{[BHMTA]2[β-Mo8O26][H3O+]2 [H2O]3}(5)was synthesized via the solvothermal reaction of(NH4)6 Mo7O24·4H2O and BHMTA.Compounds 1 and 2 were found to be crystalline 1D chain MOFs with the trilinic space group P-1.Anion structure of compound 3 is mononuclear and compound 4 is dinuclear.Compound 5 was polyoxometalates(POM)with the crystal monoclinic space group P21/n.At the same time,compounds 1,2 and 5 showed good adsorption properties for MB and RhB in aqueous solution,and selectively captures of MB from binary mixtures of MB/MO and MB/RhB.
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