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One-pot solvothermal treatments of Dy(NO3)3·6H2O,HL(4-[3-methyl-5-(pyridin-4-yl)-1,2,4-triazol-4-yl]benzoic acid)and H2atpa(2-aminoterephthalic acid)in H2O/CH3CN(V/V=1∶1)yielded a 2D network,Dy(L)(atpa)(H2O)2]n·1.5nH2O(Dy-NH2BDC).