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A two-dimensional(2D)metal-organic framework(MOF){[Cu(Dcbb)(bpe)]·OH·2H2O·}n(1)has been synthesized from CuCl2 and a zwitterionic ligand H2DcbbBr in the presence of bpe(H2DcbbBr = 1-(3,5-dicarboxybe-nzyl)-4,4-bipyridinium bromide,bpe = 1,2-bis(4-pyridyl)ethylene).