【摘 要】
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The Friedel-Crafis reaction is one of the most important carbon-carbon bond forming reactions in organic synthesis.1 To the best of our knowledge, there are only a few asymmetric reactions of indol wi
【机 构】
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College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, Henan 450052,China
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The Friedel-Crafis reaction is one of the most important carbon-carbon bond forming reactions in organic synthesis.1 To the best of our knowledge, there are only a few asymmetric reactions of indol with β,γ-unsaturated α-ketoesters catalyzed by chiral metal complexes.2 So, we try to use dinuclear Zinc complexes to catalyze this reaction,3 and good results have been achieved.
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