【摘 要】
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Kinetic isotope effects (KIEs) has long been utilized to determine the rate-limiting step or to be a spin-state reactivity probe in hydroxylation of organic sub
【机 构】
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AdvancedCatalyticEngineeringResearchCenteroftheMinistryofEducation,HunanUniversity,Changsha410082
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Kinetic isotope effects (KIEs) has long been utilized to determine the rate-limiting step or to be a spin-state reactivity probe in hydroxylation of organic substrates catalyzed by metalloporphyrins with stoichiometric oxidants [1],In this paper,we firstly used KIEs to study the mechanism of iron porphyrin complex catalyzed oxidation of cyclohexane with molecular oxygen.
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