Rhodium-catalyzed desymmetrization of cyclohexadienones is an efficient method for the asymmetric synthesis of hydrobenzofurans.The newly reported density Functional theory(DFT)method MN 12-L is used
The mechanism and regioselectivity of the [RhⅢCl2Cp*]2-catalyzed C-H bond functionalization and N-O bond cleavage of quinoline N-oxide with alkynes were studied by using DFT calculations,which suggest
Due to the widespread application of gold species in mitochondrial targeted chemotherapeutics,it is highly desirable to develop efficient detection methods for gold species in mitochondria,which is of