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Generally,pressure(>11-12 Gpa)and temperature(~2000 ℃)are required to achieve the formation of wurtzite and cubic boron nitride(wBN and cBN)from hexagonal boron nitride(hBN).For preparing sp3-bonded boron nitride[1](wBN,cBN)under moderate conditions,here we developed a solvothemal hot-press method,by which the phase transformation in boron nitride(BN)nanoparticles was realized at quite low temperature(250~310℃)and pressure(60~150MPa).