A Water-Soluble Single-Site Copper(Ⅱ)Complex with a Copper-Bound Carbonate Group for Electrocatalyti

来源 :2017年中西部地区无机化学化工学术研讨会 | 被引量 : 0次 | 上传用户:qdragon
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  The water-soluble copper(Ⅱ)complex of the pincer ligand L is a single-site water oxidation catalyst in aqueous solutions.The homogeneous catalysis was confirmed,showing an onset overpotential of 650 mV and a catalytic water oxidation current of 23 mA cm-2 in pH 10 carbonate buffer at 20 ℃.
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