Stabilization of fused-pentagon fullerenes by chlorination

来源 :第八届中日双边金属原子簇化合物研讨会 | 被引量 : 0次 | 上传用户：tfnpfije

【摘要】

：

【作者】

：

Yuan-Zhi Tan Su-Yuan Xie Rong-Bin Huang

【机构】

：

State Key Laboratory for Physical Chemistry of Solid Surfaces, and Department of Chemistry, College

【出处】

：

第八届中日双边金属原子簇化合物研讨会

【发表日期】

：

2010年9期

下载到本地 , 更方便阅读

下载此文赞助VIP

声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架

论文部分内容阅读

The Isolated Pentagon Rule1 is now widely accepted as a general rule for determining the stability of fullerene cages composed of hexagons and pentagons.Non-IPR (IPR = Isolated Pentagonal Ring) fullerenes violate the Isolated Pentagon Rule,so they are too reactive to be synthesized.Theoretically,the instability of fused pentagons is mainly due to the high local steric strain and insufficient aromaticity.

其他文献

Covalent-Bonded Donor/Acceptor Assemblies: Control of Charge-Transfer for the Design of Synergistic

Charge-transfer molecular assemblies comprised of electron-donors (D) and –acceptors (A) are one of the candidates for synergistic magnetic-conducting materials because of the expectation of interacti

会议

Porous Frameworks Assembled from Building Blocks

Synthesis of porous materials with novel structures is interesting research field due to their potential applications in sorption,separation,ion-exchange and host-guest materials.Characterizing the st

会议

Structures and Properties of Water under the Confinement: Observation of Ferroelectric Water Chain

Water molecules are essentially static,and ferroelectric water network can thus be expected when water molecules condense into a solid form.However,normal ice is usually not ferroelectric due to the p

会议

Molecular Magnetic Semiconductors Based on Versatile Ligands with Delocalized Sulfur-Rich Core

会议

Reactivity of Copper Active Oxygen Species

会议

Solid-State&Surface Protonics in Metal-Organic Frameworks

Direct alcohol fuel cells (DAFCs) have aroused great interest for portable electronic devices and electric vehicles due to their high power density output and low pollutant emissions.Ethanol is the mo

会议

New Inorganic Second-Order Nlo Materials Based on Metal Iodates

会议

Clusters and Electron Transfer in Cages of Porous Solids

Zinc has been loaded into microporous crystalline solids such as the silicoaluminophosphate SAPO-44 and the aluminosilicate zeolite Y through vapor reaction with the protons in the porous host materia

会议

Recent Progress in the Studies on Photo-Hydrogen-Evolving Molecular Devices Involving Pt(Ⅱ)-Based Mo

Since our original discovery in the catalytic activity of platinum(Ⅱ) complexes in H2 evolution from water,1 extensive efforts have been made to better understand the mechanism of H2 evolution reactio

会议

A Multifaceted Cage Cluster,[CoⅡ6O12(∩)X]-(X = Cl- or F-): Halide Template Effect and Frustrated Mag

会议

Stabilization of fused-pentagon fullerenes by chlorination

与本文相关的学术论文