功能配位聚合物的固相反应、结构及性质研究

来源 :第七届全国物理无机化学会议 | 被引量 : 0次 | 上传用户：liongliong485

【摘要】

：

多年来,我们在从事过渡金属配合物的固相反应、结构及非线性光学性质的研究[1,2],本报告将展示我们课题组近来的一些新进展.例如,3D配位聚合物[Ni3(oba)2(bpe)2(SO4)(H2O)4]

【作者】

：

郎建平

【机构】

：

苏州大学材料与化学化工学部,江苏省苏州市工业园区仁爱路199号,邮编215123

【出处】

：

第七届全国物理无机化学会议

【发表日期】

：

2016年5期

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多年来,我们在从事过渡金属配合物的固相反应、结构及非线性光学性质的研究[1,2],本报告将展示我们课题组近来的一些新进展.例如,3D配位聚合物[Ni3(oba)2(bpe)2(SO4)(H2O)4]·H2O的单晶在紫外光照射下发生[2+2] 环加成反应,可转化成对应的3D 配位聚合物[Ni3(oba)2(rctt-tpcb)(SO4)(H2O)4]·(H2O).

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功能配位聚合物的固相反应、结构及性质研究

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