C-H伸缩振动区域内正丙醇分子的构象研究

来源 :第14届全国化学动力学会议 | 被引量 : 0次 | 上传用户:nathon_zhwang
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以往文献中关于正丙醇分子构象异构现象的研究主要集中在C-O 和O-H 伸缩振动区域,而关于C-H 伸缩振动区域的研究工作则少见报道.本文利用偏振的拉曼光声光谱(Photoacoustic Raman Spectroscopy,PARS)技术,测量了氘代正丙醇CD3CH2CD2OH 分子中β-CH2 基团在C-H 伸缩振动区域(2800~3100cm-1)内高分辨的气相拉曼光谱,如图1 所示.
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