论文部分内容阅读
金属羰基配合物在有机合成中的应用十分广泛,它可以活化多种单键和不饱和键,从而催化多种有机反应,为构造新型化合物分子提供了许多直接而有效的途径[1-2].
烃基取代四甲基环戊二烯基铼羰基配合物的合成及其催化Friedel-Crafts烷基化反应研究
【摘 要】
：
金属羰基配合物在有机合成中的应用十分广泛,它可以活化多种单键和不饱和键,从而催化多种有机反应,为构造新型化合物分子提供了许多直接而有效的途径[1-2].
【机 构】
：
河北师范大学化学与材料科学学院 石家庄 050024 河北医科大学基础医学院 石家庄 050017
【出 处】
：
第十九届全国金属有机化学学术讨论会
【发表日期】
：
2016年7期
其他文献
A Computational Mechanistic Study of Metal(Ir and Rh)-Catalyzed Remote C-H Functionalizations:Insigh
The metal(Ir and Rh)-catalyzed remote C-H functionalization of quinoline N-oxide was systematically investigated using density functional theory(DFT).
会议
Visible light-promoted synthesis of 4-(sulfonylmethyl)isoquinoline-1,3(2H,4H)-dionesvia a tandem rad
Visible light photoredox catalysis of radical reactions provided a new approach to access multifunctional organic compounds under very mild reaction conditions.
会议
Synthesis and Mechanistic Study of Cyclic Oxoguanidines via Zn(OTf)2-Catalyzed Guanylation/Amidation
Cyclic guanidine compounds have received much attention in biochemistry and coordination chemistry.Recently,tandem guanylation/cyclization reaction becomes a hot field because of the fast and efficien
会议
One-pot Pd-Catalyzed C=C Forming Synthesis of 1,2-Diphenylethene via Reaction of Benzaldehyde,Tosylh
Diphenylethene compounds,also known as stilbenes,have attracted much attention of researchers for their wide applications in chemistry,medicine,electronics,optics and materials science fields.
会议
One-pot Synthesis of 3-chalcogen-multi-substituted-indoles via CuI Catalyzed Three Component Reactio
3-chalcogen-multi-substituted-indoles have recently attracted considerable attention from both academia and pharmaceutical industry,due to their curative effect in a variety of diseases,such as HIV,ca
会议
Exploring the Application of A PO4-Organic-Ti Complex Compound in Commercial non-Cr Passivation Prod
Passivation is a surface treatment process for the steel industry which is designed to provide short-term(several months) corrosion protection for galvanized sheet or galvalume sheet.
会议
Synthesis and Characterization of Heterobimetallic Organolanthanide Complexes Bearing N-Heterocyclic
The family of N-heterocyclic carbene rare earth-metal complexes is expanding rapidly rely on a diverse range of NHC-based ligands for steric and electronic control.
会议
Ligand-Controlled Cobalt-Catalyzed Transfer Hydrogenation of Alkynes:Stereodivergent Synthesis of Za
Catalytic hydrogenation of unsaturated compounds is one of the most impactful reactions in organic synthesis.
会议
含西佛碱的金属有机配合物因其易制备、稳定性好、结构变化多样和应用多样性而在过渡金属配位化学中起到了重要的作用,尤其在生物、功能材料和催化领域的应用备受关注[1-2],但其相应的过渡金属羰基配合物的报道相对较少[3-4].
会议
含Schiff bases 的金属有机配合物因其易制备、稳定性好、结构变化多样和应用多样性而在过渡金属配位化学中起到了重要的作用,尤其在生物、功能材料和催化领域的应用备受关注[1-2],但其相应的过渡金属羰基配合物的报道相对较少[3-4].
会议