This talk introduce the recent progress of microfluidic technique and its great power in controllable fabrication of advanced functional polymeric materials.The contents range from the design and fabrication of microfluidic devices,the fundamentals and strategies for controllable microfluidic generation of multiphase liquid systems(e.g.discrete multiple emulsions1 and continuous laminar multi-flow systems),and the use of these liquid systems with elaborate combination of their structures and compositions for controllable fabrication of advanced functional polymeric materials1(e.g.solid microparticles,porous microparticles,hollow microcapsules,core-shell microcapsules,hole-shell microcapsules,multicompartmental microcapsules,microfibers,in-chip membranes and microvavles,and so on).Most of the contents in this talk are the research results of the authors group on advanced functional materials fabricated with microfluidics since 2007.All the contents introduce the design concepts and fabrication strategies of advanced functional polymeric materials with microfluidics by combining the structures with the compositions of multiphase liquid systems to achieve advanced and novel functions.