Mechanistic Insights into the Rh(Ⅱ)-Catalyzed Ring Expansion of Aryl Azides to Access N-heterocycles

来源 :第十二届全国物理有机化学学术会议 | 被引量 : 0次 | 上传用户：panxihuanhe

【摘要】

：

　　Recently,the direct amination1 of C-H bonds to construct C-N bonds via metal nitrenes2 catalyzed by transition metal catalysts has attracted significant int

【作者】

：

Dafang Gao Xiaoguang Bao

【机构】

：

CollegeofChemistry,ChemicalEngineeringandMaterialsScience,SoochowUniversity,199Ren-AiRoad,SuzhouIndu

【出处】

：

第十二届全国物理有机化学学术会议

【发表日期】

：

2017年10期

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　　Recently,the direct amination1 of C-H bonds to construct C-N bonds via metal nitrenes2 catalyzed by transition metal catalysts has attracted significant interests as an alternative approach for the synthesis of N-containing heterocycles.

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Mechanistic Insights into the Rh(Ⅱ)-Catalyzed Ring Expansion of Aryl Azides to Access N-heterocycles

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