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Non-ion additive hole-transporting material(HTM)of hydrophobic oligothiophene derivative named DR3TBDTT and triphenylamine derivative of N,N′-di(3-methylphenyl)-N,Ndiphenyl-4,4-diaminobiphenyl(TPD)were used for the organic-inorganic hybrid perovskite solar cells.The power conversion efficiency(PCE)was comparable to the device using Li-TFSI doped spiro-MeOTAD.