Flexible regulation of C_3~=/C_2~= ratio in methanol-to-hydrocarbons by delicate control of acidity

来源 :Chinese Chemical Letters | 被引量 : 0次 | 上传用户:jiaofangjunonline
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Avery wide range of the C_3~=/C_2~= ratio from 0.72 to 7.56 with high C_2~= + C_3~= selectivity of around 66%in the methanol-to-hydrocarbons process can be realized over ZSM-5 catalyst in a fixed-bed reactor.We firstly conduct a single factor experiment of acidity,demonstrating that the acidity control of MTH catalyst is crucial to adjusting light olefins selectivity.Weak Br(?)nsted acid sites favor to high C_3~= selectivity(59.0%)due to the suppression of the conversion reactions from the alkene-based to arene-based cycle,while Lewis acid sites conduce to high C_2~= selectivity(39.6%) due to the promotion of the conversion reactions for the aromatics formation and steric constraints of Lewis acid sites making the aromatics crack more efficiently to C_2~=. Avery wide range of the C_3 ~ = / C_2 ~ = ratio from 0.72 to 7.56 with high C_2 ~ = + C_3 ~ = selectivity of around 66% in the methanol-to-hydrocarbons process can be realized over ZSM-5 catalyst in a fixed -bed reactor. We achieved conduct a single factor experiment of acidity, demonstrating that the acidity control of MTH catalyst is crucial to adjusting light olefins selectivity. Weak Br (?) nsted acid sites favor to high C_3 ~ = selectivity (59.0%) due to the suppression of the conversion reactions from the alkene-based to arene-based cycles, while Lewis acid sites conduce to high C_2 ~ = selectivity (39.6%) due to the promotion of the conversion reactions for the aromatics formation and steric constraints of Lewis acid sites making the aromatics crack more efficiently to C_2 ~ =.
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