论文部分内容阅读
Synthesis of poly(thiocarbonate)s from the copolymerization of epoxides and carbon disulfide (CS2) remains a tough challenge,due to inevitable oxygen-sulfur atom scrambling process.In this work,we utilized the oxygen-sulfur exchange reaction (O-S ER) to synthesize a random copolymer with monothiocarbonate and trithiocarbonate units from CS2 and phenyl glycidyl ether (PGE) via metal-free Lewis pairs.The copolymers contained monothiocarbonate and trithiocarbonate units of which the molar fraction could be tuned by varying either the types of Lewis pairs or the reaction temperature.Keeping track on the intermediate provided an insight in the process of O-S ER and thus gave a hint to control the product structure.Production and consumption of phenyl thioglycidyl ether was the key process to regulate the chain structure.Remarkably,the oxygen atoms of PGE could be excluded out of the chain,resulting in the nearly complete production of poly(trithiocarbonate)s.Correspondingly,the refractive index of this kind of copolymer could be regulated in a wide range of 1.73-1.79 (at 590 nm).