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微波加热因其反应时间短、产量高、副反应少、安全等特点,使微波技术作为一种新技术在有机合成中得到广泛的应用,已成为有机合成领域的研究热点,也为聚合反应的研究提供了新的思维方法。简要介绍了微波反应器的研究进展,对国内外微波辐射在高分子聚合反应中的研究现状进行了综述,主要包括微波辅助活性可控的自由基聚合、开环聚合、逐步聚合和以离子液体为介质的聚合,并指出了微波应用于聚合反应中所需要解决的问题。
Due to its short reaction time, high yield, few side reactions and safety, microwave heating has been widely used in organic synthesis as a new technology and has become a research hotspot in the field of organic synthesis. Research provides a new way of thinking. The research progress of microwave reactor is briefly introduced. The research status of microwave radiation in polymer polymerization at home and abroad is reviewed. The main contents include microwave radical assisted radical polymerization, ring-opening polymerization, gradual polymerization and ionic liquids For the polymerization of the media, and pointed out that the microwave used in the polymerization reaction need to be resolved.